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Solutions - ISC Class 12 Chemistry Questions with Answers, Page 3

75 past-paper questions on Solutions from ISC Class 12 Chemistry papers (2027-2018), newest first, in full. Questions 41-60 are on this page, 20 to a page. Tap "Show answer" under a question to see its answer.

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2025 · 5 marks · Short answerOpen: Answer the following questions: An aqueous solution is made by dissolving of…
Answer the following questions:
(a)[2.0]
An aqueous solution is made by dissolving $10\text{ g}$ of glucose ($\text{C}_6\text{H}_{12}\text{O}_6$) in $90\text{ g}$ of water at $300\text{ K}$. If the vapour pressure of pure water at $300\text{ K}$ is $32\cdot8\text{ mm Hg}$, what would be the vapour pressure of the solution? (Given: $\text{C} = 12, \text{H} = 1$ and $\text{O} = 16$)
(b)[2.0]
A solution containing $12\cdot5\text{ g}$ of a non-electrolyte solute in $175\text{ g}$ of water gave boiling point of $100\cdot70^\circ\text{C}$. Calculate the molecular mass of the solute. (Given: $K_b$ for water $= 0\cdot52\text{ K kg mol}^{-1}$)
(c)[1.0]
Why are soda water bottles sealed under high pressure?

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2024 · 3 marks · Case basedOpen: During the winter season in a particular year, Kashmir experienced heavy…
During the winter season in a particular year, Kashmir experienced heavy snowfall. It was an unexpected snowfall. Thousands of visitors were stranded because it was dangerous to travel on snowy roads and vehicles could not move as water froze in the car radiators. In such conditions officials decided to sprinkle rock salt or $\text{CaCl}_2$ on roads.
Read the passage given below carefully and answer the questions that follow.
(i)[1.0]
Why was it decided to sprinkle rock salt or $\text{CaCl}_2$ on the roads?
(ii)[1.0]
A mixture of ethylene glycol and water is used as coolant in car radiators. Why?
(iii)[1.0]
How many grams of ethylene glycol ($\text{mol. wt.} = 62\text{ g mol}^{-1}$) should be added to $10\text{ kg}$ of water so that the solution freezes at $-10^\circ\text{C}$? ($K_f$ for water $= 1\cdot86\text{ K kg mol}^{-1}$)

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2024 · 2 marks · NumericalOpen: If of an aqueous solution of a protein contains of protein, the osmotic…
If $200\text{ cm}^3$ of an aqueous solution of a protein contains $1\cdot26\text{ g}$ of protein, the osmotic pressure of the solution at $300\text{ K}$ is found to be $2\cdot57 \times 10^{-3}\text{ atm}$. Calculate the molar mass of protein. ($R = 0\cdot0821\text{ L atm K}^{-1}\text{ mol}^{-1}$)

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2024 · 3 marks · Short answerOpen: Water vapour and liquid water are in equilibrium in a container. At room…
Water vapour and liquid water are in equilibrium in a container. At room temperature, the vapour pressure of water is $25\text{ mm of Hg}$. The volume of water is $V\text{ ml}$.
(i)[1.5]
What will be the vapour pressure of water if the volume of water is reduced to $V/4\text{ ml}$ without any change in temperature? Give a reason.
(ii)[1.5]
Will there be a change in vapour pressure if more water (at room temperature) is added to the container? Give a reason.

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2024 · 3 marks · NumericalOpen: An aqueous solution containing of barium chloride in of water boils at …
An aqueous solution containing $12\cdot50\text{ g}$ of barium chloride in $1000\text{ g}$ of water boils at $373\cdot0834\text{ K}$. Calculate the degree of dissociation of barium chloride. Given $K_b$ for $\text{H}_2\text{O} = 0\cdot52\text{ K kg mol}^{-1}$; molecular mass of $\text{BaCl}_2 = 208\cdot34\text{ g mol}^{-1}$

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2024 · 3 marks · Case basedOpen: When two solutions are separated by a semi-permeable membrane, the solvent…
When two solutions are separated by a semi-permeable membrane, the solvent molecules move from a solution of lower molar concentration to a solution of higher molar concentration through osmosis.
Read the passage given below and answer the questions that follow.
(i)[1.0]
Samar removed the outer hard shell of two different eggs while cooking at home. He then placed one egg in pure water and the other egg in saturated solution of sucrose. What change is he likely to observe in the eggs after few hours?
(ii)[1.0]
Which solution, hypertonic or hypotonic, has a higher amount of solute in same quantity of solution?
(iii)[1.0]
A $5\%$ aqueous solution of glucose (molar mass $= 180\text{ g mol}^{-1}$) is isotonic with $1\cdot66\%$ aqueous solution of urea. Calculate the molar mass of urea.

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2024 · 2 marks · NumericalOpen: John was making noodles in boiling water. When he added common salt ( ) to…
John was making noodles in boiling water. When he added common salt ($\text{NaCl}$) to boiling water, the water stopped boiling for a short while. If John had added $15\cdot0\text{ g}$ of $\text{NaCl}$ to $250\cdot0\text{ g}$ of water, calculate the boiling point of solution assuming that $\text{NaCl}$ dissociates completely in water. ($K_b$ for water $= 0\cdot512\text{ K kg mol}^{-1}$, molecular mass of $\text{NaCl} = 58\cdot44\text{ g mol}^{-1}$).

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2023 · 2 marks · NumericalOpen: Calculate the mass of ascorbic acid (molecular mass ) that should be dissolved…
Calculate the mass of ascorbic acid (molecular mass $= 176\text{ g/mol}$) that should be dissolved in $155\text{ g}$ of acetic acid to cause a depression of freezing point by $1\cdot15\text{ K}$. Assume that ascorbic acid does not dissociate or associate in the solution. ($K_f$ for acetic acid $= 3\cdot9\text{ K kg/mol}$)

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2023 · 3 marks · NumericalOpen: When of benzoic acid is dissolved in of benzene, it shows a depression in…
When $2\text{ g}$ of benzoic acid is dissolved in $25\text{ g}$ of benzene, it shows a depression in freezing point equal to $1\cdot62\text{ K}$. Molal depression constant ($K_f$) of benzene is $4\cdot9\text{ K kg mol}^{-1}$ and molecular weight of benzoic acid $= 122\text{ g/mol}$. What will be the percentage association of the benzoic acid? (Benzoic acid forms dimer when dissolved in benzene.)

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2023 · 4 marks · MatchOpen: Match the following:
Match the following:
Column A
  • (i)Phenol
  • (ii)Ethylenediamine
  • (iii)Colligative property
  • (iv)Amino acid
Column B
  • (a)Osmotic pressure
  • (b)Zwitter ion
  • (c)Neutral $\text{FeCl}_3$ solution
  • (d)Bidentate ligand.

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2023 · 3 marks · NumericalOpen: An aqueous solution containing of barium chloride in of water boils at …
An aqueous solution containing $12\cdot48\text{ g}$ of barium chloride in $1000\text{ g}$ of water boils at $373\cdot0832\text{ K}$. Calculate the degree of dissociation ($\alpha$) of barium chloride. $K_b$ for $\text{H}_2\text{O} = 0\cdot52\text{ K kg mol}^{-1}$, molecular mass of $\text{BaCl}_2 = 208\cdot34\text{ g mol}^{-1}$.

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2022 · 2 marks · Short answerOpen: An aqueous solution containing one gram of urea (molecular weight = 60) boils…
An aqueous solution containing one gram of urea (molecular weight = 60) boils at 100.25oC. The same solution freezes at -0.894 oC. The aqueous solution containing 3 gram of glucose (Molecular weight = 180) in the same volume of solution:
(i)
What is the boiling point of glucose?
  • (a)100.75 oC
  • (b)100.50 oC
  • (c)100.25 oC
  • (d)100.08 oC
(ii)
What is the freezing point of glucose?
  • (a)+0.894 oC
  • (b)-0.894 oC
  • (c)+0.447 oC
  • (d)-0.447 oC

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