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Write the chemical equation for the following.

Benzene diazonium chloride is treated with ice cold solution of aniline in acidic medium.

Chemistry20191 markReaction

Answer

Answer

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Equation: $\mathrm{C_{6}H_{5}N_{2}Cl} + \mathrm{C_{6}H_{5}NH_{2}} \xrightarrow{\text{acidic}\text{ }\text{medium}\text{,}\text{ }\text{273-278}\text{ }\text{K}} \mathrm{C_{6}H_{5}N=NC_{6}H_{4}NH_{2}} + \mathrm{HCl}$

Reaction: Coupling reaction

Product: 4-aminoazobenzene (p-aminoazobenzene)

Benzene diazonium chloride couples with aniline at the para position to give the yellow dye p-aminoazobenzene.
Diazonium salts

From ISC 2019 Chemistry Paper 1, question 14(iii).