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Chemistry20261 markMCQCoordination CompoundsTool: Coordination complex analyser

Choose the correct option.

In the complexes, [Fe(CN)₆]⁴⁻ and [Pt(en)(H₂O)₂Br(NO₂)]²⁺, the respective oxidation numbers of…

In the complexes, $[\text{Fe}(\text{CN})_6]^{4-}$ and $[\text{Pt}(\text{en})(\text{H}_2\text{O})_2\text{Br}(\text{NO}_2)]^{2+}$, the respective oxidation numbers of central metal atoms are:
  • (a)+3 and +4
  • (b)+2 and +2
  • (c)+2 and +4
  • (d)+3 and +2

Answer

Answer

Correct option: (c)

Answer: (c) +2 and +4 In $[\mathrm{Fe(CN)_6}]^{4-}$: $x - 6 = -4$, so $x = +2$. In $[\mathrm{Pt(en)(H_2O)_2Br(NO_2)}]^{2+}$: $x + 0 + 0 - 1 - 1 = +2$, so $x = +4$.