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Answer the following.

Complete and balance the following equations:

Chemistry20202 marksComplete
(i)[1.0]
$\text{C}_6\text{H}_5\text{NH}_2 + \text{CH}_3\text{COCl} \rightarrow \underline{\hspace{2em}} + \underline{\hspace{2em}}$
(ii)[1.0]
$\text{C}_2\text{H}_5\text{NH}_2 + \text{HNO}_2 \rightarrow \underline{\hspace{2em}} + \underline{\hspace{2em}} + \underline{\hspace{2em}}$

Answer

Answer (i)

AI

Equation: $\mathrm{C_{6}H_{5}NH_{2}} + \mathrm{CH_{3}COCl} \xrightarrow{\text{pyridine}} \mathrm{C_{6}H_{5}NHCOCH_{3}} + \mathrm{HCl}$

Acetanilide and hydrogen chloride are formed (acetylation).

Answer (ii)

AI

Equation: $\mathrm{C_{2}H_{5}NH_{2}} + \mathrm{HNO_{2}} \xrightarrow{\mathrm{NaNO_{2}}\text{ }\text{+}\text{ }\text{HCl}} \mathrm{C_{2}H_{5}OH} + \mathrm{N_{2}} + \mathrm{H_{2}O}$

Ethanol, nitrogen and water are formed.
Aliphatic Amines

From ISC 2020 Chemistry Paper 1, question 7(b).

Check your working with the Chemical equation balancer: balance any equation, ionic and redox ones too, with the atom count on each side.