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Which of the following electrolytes is least effective in causing flocculation of positively…

Chemistry20201 markMCQ
Which of the following electrolytes is least effective in causing flocculation of positively charged ferric hydroxide sol?
  • (1)$\text{K}_3[\text{Fe}(\text{CN})_6]$
  • (2)$\text{K}_2\text{CrO}_4$
  • (3)$\text{K}_4[\text{Fe}(\text{CN})_6]$
  • (4)$\text{KBr}$

Answer

Answer

AI

Correct option: (4)

Answer: (4) $\mathrm{KBr}$ The sol is positively charged, so flocculation is caused by anions; by the Hardy-Schulze rule, the higher the charge on the anion the more effective it is. $\mathrm{Br^-}$ is monovalent, hence $\mathrm{KBr}$ is least effective.
Surface Chemistry

From ISC 2020 Chemistry Paper 1, question 1(b)(iii).