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Chemistry20251 markAssertion-reasond-and f-Block Elements

Study the Assertion and Reason and choose the correct option.

The Zr-Hf pair of elements has the same value of atomic radii though Zr and Hf are placed in…

Assertion: The $\text{Zr}$-$\text{Hf}$ pair of elements has the same value of atomic radii though $\text{Zr}$ and $\text{Hf}$ are placed in different periods in the periodic table.

Reason: The lanthanoid contraction prevents the expected increase in atomic radii of $\text{Hf}$.

  • (a)Both Assertion and Reason are true and Reason is the correct explanation for Assertion.
  • (b)Both Assertion and Reason are true but Reason is not the correct explanation for Assertion.
  • (c)Assertion is true and Reason is false.
  • (d)Both Assertion and Reason are false.

Answer

Answer

Correct option: (a)

Answer: (a) Both Assertion and Reason are true and Reason is the correct explanation for Assertion. The lanthanoid contraction (poor shielding by $4f$ electrons) makes the radius of Hf almost the same as that of Zr.