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How will you bring about the following conversion?

Give a balanced chemical equation to convert methyl cyanide to ethyl alcohol.

Chemistry20181 markConversion

Answer

Answer

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Equations: $\mathrm{CH_{3}CN} + 2\mathrm{H_{2}} \xrightarrow{\text{Na}\text{/}\mathrm{C_{2}H_{5}OH}\text{ }\text{(or}\text{ }\mathrm{LiAlH_{4})}} \mathrm{CH_{3}CH_{2}NH_{2}}$ $\mathrm{CH_{3}CH_{2}NH_{2}} + \mathrm{HNO_{2}} \xrightarrow{\mathrm{NaNO_{2}}\text{/}\text{HCl}\text{,}\text{ }\text{273}\text{ }\text{K}} \mathrm{CH_{3}CH_{2}OH} + \mathrm{N_{2}} + \mathrm{H_{2}O}$

Methyl cyanide is reduced to ethylamine, which is converted to ethyl alcohol with nitrous acid.
Cyanides and Isocyanides

From ISC 2018 Chemistry Paper 1, question 14(b).

Check your working with the Chemical equation balancer: balance any equation, ionic and redox ones too, with the atom count on each side.