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Chemistry20261 markReactionHaloalkanes and Haloarenes

Write the chemical equation for the following.

CH₃CH₂CH₂COOAg + Br₂ xrightarrow[Heat]CCl₄ \underline{\hspace{2em}}

$\mathrm{CH_3CH_2CH_2COOAg + Br_2 \xrightarrow[Heat]{CCl_4}}$ \underline{\hspace{2em}}

Answer

Answer

Equation: $\mathrm{CH_{3}CH_{2}CH_{2}COOAg} + \mathrm{Br_{2}} \xrightarrow{\mathrm{CCl_{4}}\text{,}\text{ }\text{heat}} \mathrm{CH_{3}CH_{2}CH_{2}Br} + \mathrm{AgBr} + \mathrm{CO_{2}}$

Product: 1-bromopropane

Hunsdiecker reaction: the silver salt loses $\mathrm{CO_2}$ and the main organic product is 1-bromopropane, $\mathrm{CH_3CH_2CH_2Br}$.