Prashnikaप्रश्निका

Distinguish two organic compounds

“Give a chemical test to distinguish between…” - type the two compounds and get every test that tells them apart, with the reagent and what each one shows.

Try: propanal and propanoneethanol and phenolethanamine and N-methylethanamineethanoic acid and ethanolpropan-2-ol and 2-methylpropan-2-ol

Answer

Warm or treat each with I2 and NaOH, warm: propanal gives no change, propanone gives yellow precipitate of iodoform, CHI3.

Every test that tells them apart

TestReagentpropanalpropanone
IodoformI2 and NaOH, warmno changeyellow precipitate of iodoform, CHI3
TollensTollens' reagent (ammoniacal AgNO3), warmsilver mirrorno change
FehlingFehling's solution, warmred-brown precipitate of Cu2Ono change
SchiffSchiff's reagentpink colour returnsno change

The two compounds

propanal (C3H6O)

aldehyde

propanone (C3H6O)

ketone, methyl ketone or CH3CHO

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