Prashnikaप्रश्निका

Distinguish two organic compounds

“Give a chemical test to distinguish between…” - type the two compounds and get every test that tells them apart, with the reagent and what each one shows.

Try: propanal and propanoneethanol and phenolethanamine and N-methylethanamineethanoic acid and ethanolpropan-2-ol and 2-methylpropan-2-ol

Answer

Warm or treat each with I2 and NaOH, warm: propan-2-ol gives yellow precipitate of iodoform, CHI3, 2-methylpropan-2-ol gives no change.

Every test that tells them apart

TestReagentpropan-2-ol2-methylpropan-2-ol
IodoformI2 and NaOH, warmyellow precipitate of iodoform, CHI3no change
LucasLucas reagent (conc. HCl + anhydrous ZnCl2)turbidity in about 5 minutesturbidity at once

The two compounds

propan-2-ol (C3H8O)

alcohol, CH3CH(OH)-

2-methylpropan-2-ol (C4H10O)

alcohol

Practise on real ISC questions

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