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How will you bring about the following conversion?

Phenol to chlorobenzene

Chemistry20261 markConversion

Answer

Answer

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Equations: $\mathrm{C_{6}H_{5}OH} + \mathrm{Zn} \xrightarrow{\text{heat}} \mathrm{C_{6}H_{6}} + \mathrm{ZnO}$ $\mathrm{C_{6}H_{6}} + \mathrm{Cl_{2}} \xrightarrow{\text{anhydrous}\text{ }\mathrm{FeCl_{3}}} \mathrm{C_{6}H_{5}Cl} + \mathrm{HCl}$

Phenol to chlorobenzene: reduction with zinc dust to benzene, then chlorination.
Phenols

From ISC 2026 Improvement Chemistry Paper 1, question 15(iii).