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Chemistry20261 markAssertion-reasonAliphatic Ethers

Study the Assertion and Reason and choose the correct option.

Methoxy ethane reacts with HI at 373 K to give ethanol and iodomethane.

Assertion: Methoxy ethane reacts with $\text{HI}$ at $373\text{ K}$ to give ethanol and iodomethane.

Reason: Reaction of unsymmetrical ether with $\text{HI}$ follows $\text{S}_\text{N}2$ mechanism.

  • (a)Both Assertion and Reason are true and Reason is the correct explanation for Assertion.
  • (b)Both Assertion and Reason are true but Reason is not the correct explanation for Assertion.
  • (c)Assertion is true and Reason is false.
  • (d)Both Assertion and Reason are false.

Answer

Answer

Official answer key

Correct option: (a)

Answer: (a) Both Assertion and Reason are true and Reason is the correct explanation for Assertion. In an unsymmetrical ether with primary alkyl groups, $\mathrm{I^-}$ attacks the smaller alkyl group by the $\mathrm{S_N2}$ route, giving $\mathrm{CH_3I}$ and $\mathrm{C_2H_5OH}$.