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How will you bring about the following conversion?

Formaldehyde to ethanol

Chemistry20261 markConversion

Answer

Answer

Official answer key

Equations: $\mathrm{HCHO} + \mathrm{CH_{3}MgBr} \xrightarrow{\text{dry}\text{ }\text{ether}} \mathrm{CH_{3}CH_{2}OMgBr}$ $\mathrm{CH_{3}CH_{2}OMgBr} + \mathrm{H_{2}O} \xrightarrow{\text{hydrolysis}} \mathrm{CH_{3}CH_{2}OH} + \mathrm{Mg(OH)Br}$

Methylmagnesium bromide adds to formaldehyde; hydrolysis of the adduct gives ethanol.
Aldehydes and Ketones

From ISC 2026 Specimen Chemistry Paper 1, question 6(ii).