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Chemistry20261.5 marksIdentifyAliphatic Amines

Identify the compounds in the following.

C₂H₅Cl xrightarrowalc. KCN [A] xrightarrow4[H] [B] xrightarrow[heat]CHCl₃ + alc. KOH [C]

$\text{C}_2\text{H}_5\text{Cl} \xrightarrow{\text{alc. KCN}} [\text{A}] \xrightarrow{4[\text{H}]} [\text{B}] \xrightarrow[\text{heat}]{\text{CHCl}_3 + \text{alc. KOH}} [\text{C}]$

Answer

Answer

A - propanenitrile: CH3CH2CN

B - propan-1-amine: CH3CH2CH2NH2

C - 1-isocyanopropane (propyl isocyanide): CH3CH2CH2NC

A = propanenitrile ($\mathrm{C_2H_5CN}$) B = propan-1-amine ($\mathrm{CH_3CH_2CH_2NH_2}$) C = propyl isocyanide ($\mathrm{CH_3CH_2CH_2NC}$)