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In the dehydration of alcohols to alkenes by heating with concentrated sulphuric acid, the…

Chemistry20181 markMCQ
In the dehydration of alcohols to alkenes by heating with concentrated sulphuric acid, the initiation step is:
  • (1)formation of carbocation
  • (2)formation of an ester
  • (3)protonation of alcohol molecule
  • (4)elimination of water

Answer

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Correct option: (3)

Answer: (3) protonation of alcohol molecule The first step is the protonation of the alcohol by $\mathrm{H_2SO_4}$ to form an oxonium ion; loss of water then gives the carbocation.
Alcohols

From ISC 2018 Chemistry Paper 1, question 1(b)(iv).