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Chemistry20222 marksCase basedHaloalkanes and Haloarenes

Choose the correct option.

The reaction: CH₃Br + OH⁻ → CH₃OH + Br⁻ The expected mechanism of the above reaction is: The above…

The reaction: $\text{CH}_3\text{Br} + \text{OH}^- \rightarrow \text{CH}_3\text{OH} + \text{Br}^-$
(i)[1]
The expected mechanism of the above reaction is:
  • (a)SN1 mechanism
  • (b)SN2 mechanism
  • (c)SE1 mechanism
  • (d)SE2 mechanism
(ii)[1]
The above reaction is:
  • (a)Elimination reaction
  • (b)Nucleophilic addition reaction
  • (c)Nucleophilic substitution reaction
  • (d)Electrophilic substitution reaction

Answer

Answer (i)

Correct option: (b)

Answer: (b) $\mathrm{S_N2}$ mechanism Methyl bromide is a primary (methyl) halide with no steric hindrance, so $\mathrm{OH^-}$ attacks from the back in a single step.

Answer (ii)

Correct option: (c)

Answer: (c) Nucleophilic substitution reaction The nucleophile $\mathrm{OH^-}$ replaces the halogen $\mathrm{Br}$ on the sp$^3$ carbon.