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Name of the type of isomerism exhibited by the following pairs of compounds: (1) and (2) and (3)…
(i)
Name of the type of isomerism exhibited by the following pairs of compounds:
(1) $[\text{Co}(\text{ONO})(\text{NH}_3)_5]^{2+}$ and $[\text{Co}(\text{NO}_2)(\text{NH}_3)_5]^{2+}$
(2) $[\text{Cr}(\text{H}_2\text{O})_4\text{Cl}_2]\text{Cl}\cdot2\text{H}_2\text{O}$ and $[\text{Cr}(\text{H}_2\text{O})_5\text{Cl}]\text{Cl}_2\cdot\text{H}_2\text{O}$
(3) $[\text{Co}(\text{NH}_3)_6][\text{Cr}(\text{CN})_6]$ and $[\text{Cr}(\text{NH}_3)_6][\text{Co}(\text{CN})_6]$
(ii)
Using the valence bond approach, predict the shape, hybridisation and magnetic behaviour of $[\text{Ni}(\text{CO})_4]$. (at. no. of $\text{Ni} = 28$)
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From ISC 2020 Chemistry Paper 1, question 17(b).